Nickeloan pyrite from Prangenhaus quarry, Niederberg area, Germany—A short communication     

Udo Harms 《Chemie der Erde / Geochemistry》2009,69(3):279-285

The mineral chemistry of two nickeloan pyrite samples from the Prangenhaus quarry, Wülfrath, is presented. Sample PRH 5: main zone=4.32-9.7 wt% Ni (0.089-0.202 atoms per formula unit (a.p.f.u.)), 0.21-1.31 wt% Co (0.004-0.027 a.p.f.u.); rim zone=11.76-22.38 wt% Ni (0.244-0.466 a.p.f.u. ), 1.35-8.16 wt% Co (0.028-0.168 a.p.f.u.). Sample PRH 6: 6.75-11.33 wt% Ni (0.139-0.234 a.p.f.u.), 0.86-2.46 wt% Co (0.018-0.051 a.p.f.u.). Estimated Fe/Ni and Fe/Co ratios of the hydrothermal fluids forming the nickeloan pyrite point to very local fluctuations in the chemistry of the ore forming fluids in the Prangenhaus quarry. The presence of nickeloan pyrite indicates formation temperatures below 137 °C, which is in accordance with earlier findings of formation temperatures for sphalerite (60-130 °C) in the Niederberg area.  相似文献   

Geochronology/geochemistry of the Washan dioritic porphyry associated with Kiruna-type iron ores,Middle-Lower Yangtze River Valley,eastern China: implications for petrogenesis/mineralization     

《International Geology Review》2012,54(11):1332-1352

The Early Cretaceous Washan dioritic porphyry is spatially and temporally associated with Kiruna-type iron oxide deposits in the Ningwu basin, Middle-Lower Yangtze River Valley (MLYRV). We present new LA-ICP-MS U–Pb dating + zircon Lu–Hf isotopic studies, as well as bulk-rock major + trace element and Sr + Nd isotopic compositions of the porphyry. LA-ICP-MS U–Pb zircon analyses suggest that the pluton formed at 130.8?±?0.9 Ma. Analysed zircon ?_Hf(t) values range from –7.0 to –4.1. The dioritic rocks are significantly enriched in Pb and light rare earth elements, relative to high-field strength elements (Nb + Ti), coupled in the absence of significant Eu anomalies. They exhibit age-corrected ?_Nd(t) (t?=?130 million years) values of??3.5 to??3.9 and initial ⁸⁷Sr/⁸⁶Sr ratios of 0.70553–0.70653. The ore-bearing dioritic porphyry was derived from a parental basaltic liquid that was produced by partial melting of an enriched spinel-facies lherzolite in the Yangtze lithospheric mantle. This basaltic melt underwent a fractionation of plagioclase and clinopyroxene during ascent towards the surface, which led to the relative enrichment of iron in the residual melt. This type of magma was widespread in the MLYRV area but did not generate widespread Fe mineralization. In the Ningwu area, the dioritic magma was modified by minor assimilation of phosphorus-bearing rocks in the Yangtze upper crust. The special crustal characteristics of the Ningwu basin, i.e. phosphorus-rich strata, were likely a crucial factor controlling the formation of Kiruna-type iron oxide deposits.  相似文献   

过硫酸铵-丁二酮肟光度法测定红土镍矿中的镍   总被引：2，自引：1，他引：1  

褚宁  蒋晓光  李卫刚  王艳君 《岩矿测试》2012,31(3):479-483

红土镍矿样品用适宜比例的HCl-HNO3-HF-HClO4混合酸低温消解,待样品溶解完全后在NaOH介质中,以过硫酸铵作氧化剂将Ni2+氧化为Ni4+,使Ni4+与丁二酮肟生成可溶性酒红色络合物,采用分光光度法测定镍的含量。样品溶液中仅通过加入酒石酸钾钠作掩蔽剂,就可消除红土镍矿中其他基体元素对镍测定的干扰,避免了萃取分离操作和有机试剂对环境的污染。在优化的酸碱度、试剂加入顺序及用量、显色时间等实验条件下,镍的线性范围为0～2.0μg/mL,方法检出限为0.1 mg/g,精密度为(RSD)为0.75%～1.69%,加标回收率为95.4%～102.7%。方法用于分析红土镍矿中镍的含量,测定结果与电感耦合等离子体发射光谱法相符。该方法简便,稳定性好,仪器价格低廉,可用于批量红土镍矿样品中镍的快速准确测定。  相似文献   

辽宁弓长岭铁矿区大理岩地质地球化学特征及其成矿意义   总被引：9，自引：5，他引：4  

李厚民  刘明军  李立兴  杨秀清  陈靖  姚良德  洪学宽  姚通 《岩石学报》2012,28(11):3497-3512

弓长岭铁矿床二矿区西北部发现的含磁铁矿白云质大理岩为与条带状硅铁建造整合产出的原始沉积成因碳酸盐岩.本文对该大理岩及其蚀变岩的主量元素、微量元素、稀土元素及碳氧同位素进行了初步研究.大理岩主要化学组成CaO为30.15％～ 34.32％,MgO为9.86％～11.95％,FeOT为6.76％～15.82％;与平均显生宙石灰岩相比,弓长岭大理岩除Pb、Mn富集外,大离子亲石元素和高场强元素明显亏损;与后太古代平均澳大利亚沉积岩(PAAS)相比,弓长岭大理岩稀土元素总量低,明显正铕异常,铈负异常不明显;弓长岭大理岩δ13CV-PDB为-7.0‰～-6.0‰,Y/Ho比值既不同于海水也不同于陆源碎屑.这些特征显示大理岩形成于缺氧的海洋环境,物质来源与海底喷气热液活动有关.大理岩的沉积表明当时海水的酸碱条件已达中性-弱碱性,有利于铁胶体沉淀成矿.大理岩层不仅易于发生构造变形,而且贫铁矿形成富铁矿时迁出的硅质交代大理岩形成了阳起石岩,同时大理岩还为热液交代形成石榴石岩、绿泥石岩和镁铁闪石岩等蚀变岩提供了镁质.  相似文献   

福建建阳江墩金矿床地质特征及找矿标志     

江里跃 《福建地质》2005,24(3):154-159

建阳江墩金矿呈脉状-（长）透镜状,赋存于矿化蚀变体内或其边缘,与金矿形成关系密切的矿化蚀变体产于下元古界麻源群大金山组上段变质岩系的F6断裂蚀变带中.共发现表内金矿体9个,表外金矿体3个,规模较小,品位较高.初步认为矿床类型属于与变质热液有关的构造蚀变岩型金矿床.  相似文献   

陕西旬阳地区铅锌矿电性研究     

沈鸿雁  李庆春  王永平  薛胜利 《地球科学与环境学报》2007,29(4):416-421

采用电法勘探对陕西旬阳地区大黑山、小水河和葫芦沟地区铅锌矿做地质探讨评价,通过对该地区成矿背景和电性规律研究,成功探明大黑山1、2号矿体产状、走向和规模,圈定小水河和葫芦沟地区多处有找矿意义的异常,同时总结出该地区铅锌矿电性突出,具有"高视电阻率、高视极化率"特征。  相似文献   

Platinum-group minerals from the Jinbaoshan Pd–Pt deposit,SW China: evidence for magmatic origin and hydrothermal alteration     

Christina Yan Wang  Hazel M. Prichard  Mei-Fu Zhou  Peter C. Fisher 《Mineralium Deposita》2008,43(7):791-803

The Jinbaoshan Pt–Pd deposit in Yunnan, SW China, is hosted in a wehrlite body, which is a member of the Permian (∼260 Ma) Emeishan Large Igneous Province (ELIP). The deposit is reported to contain one million tonnes of Pt–Pd ore grading 0.21% Ni and 0.16% Cu with 3.0 g/t (Pd + Pt). Platinum-group minerals (PGM) mostly are ∼10 μm in diameter, and are commonly Te-, Sn- and As-bearing, including moncheite (PtTe₂), atokite (Pd₃Sn), kotulskite (PdTe), sperrylite (PtAs₂), irarsite (IrAsS), cooperite (PtS), sudburyite (PdSb), and Pt–Fe alloy. Primary rock-forming minerals are olivine and clinopyroxene, with clinopyroxene forming anhedral poikilitic crystals surrounding olivine. Primary chromite occurs either as euhedral grains enclosed within olivine or as an interstitial phase to the olivine. However, the intrusion has undergone extensive hydrothermal alteration. Most olivine grains have been altered to serpentine, and interstitial clinopyroxene is often altered to actinolite/tremolite and locally biotite. Interstitial chromite grains are either partially or totally replaced by secondary magnetite. Base-metal sulfides (BMS), such as pentlandite and chalcopyrite, are usually interstitial to the altered olivine. PGM are located with the BMS and are therefore also interstitial to the serpentinized olivine grains, occurring within altered interstitial clinopyroxene and chromite, or along the edges of these minerals, which predominantly altered to actinolite/tremolite, serpentine and magnetite. Hydrothermal fluids were responsible for the release of the platinum-group elements (PGE) from the BMS to precipitate the PGM at low temperature during pervasive alteration. A sequence of alteration of the PGM has been recognized. Initially moncheite and atokite have been corroded and recrystallized during the formation of actinolite/tremolite, and then, cooperite and moncheite were altered to Pt–Fe alloy where they are in contact with serpentine. Sudburyite occurs in veins indicating late Pd mobility. However, textural evidence shows that the PGM are still in close proximity to the BMS. They occur in PGE-rich layers located at specific igneous horizons in the intrusion, suggesting that PGE were originally magmatic concentrations that, within a PGE-rich horizon, crystallized with BMS late in the olivine/clinopyroxene crystallization sequence and have not been significantly transported during serpentinization and alteration.  相似文献   

深海水泵与储料罐组合采矿硬管输送系统研究     

徐绍军  徐海良 《海洋工程》2007,25(3):73-77,82

通过对沙浆泵接力输送和水泵与储料罐组合输送两种深海采矿输送方法进行分析,可知采用沙浆泵对矿石流体进行接力输送的方法,沙浆泵容易磨损破坏,安装维护困难;而水泵与储料罐组合的输送方法在理论上具有扬程高,输送量大,能长期可靠地工作,当应用于深海硬管采矿系统时,输送设备的主水泵和主要动力设备安装于采矿船上,相对于深海工作,在技术上易于实现,工作可靠,操作和维修方便。并对四种输送系统参数进行分析,水泵与储料罐组合的输送方法在理论上可行,采用现有技术容易实现,是一种具有应用前景的深海采矿输送方法。  相似文献   

青海锡铁山碳质片岩型铅-锌矿床的矿化结构特征   总被引：1，自引：0，他引：1  

赵向东  李峰  坚润堂  邹国富 《矿产与地质》2008,22(5):405-411

文章应用地质、地球化学分析,对锡铁山矿区新发现的（碳质）片岩型矿体的矿化结构、矿体类型及其典型元素分带特征进行综合研究,得出以下结论：锡铁山矿床具“双层结构”,由大理岩型矿体和碳质片岩型矿体组成;碳质片岩型矿体主要赋存于滩间山群沉积岩组中上部,产出层位高于大理岩型矿体;碳质片岩型矿体的倒转型热水喷流沉积结构与含矿层倒转有关。研究表明,矿区找矿潜力巨大。  相似文献   

福建莆田泗洋铅锌矿地质特征及成因探讨     

梁乐辉 《福建地质》2008,27(3):259-266

泗洋铅锌矿产于南园组第三段中酸-酸性火山碎屑岩中,矿体呈透镜状、脉状,受断裂构造、火山环状构造控制。成矿与中生代岩浆侵入及火山活动紧密相关,为中低温岩浆-火山热液型矿床。  相似文献